Tris(1,10-phenanthroline-κ2 N,N′)iron(II) μ-oxido-bis[trichloridoferrate(III)] ethanol hemisolvate

نویسندگان

  • Zhan-Xian Li
  • Ming-Ming Yu
  • Yu-Na Zhang
  • Liu-He Wei
چکیده

The title compound, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O]·0.5CH(3)CH(2)OH, consists of one [Fe(phen)(3)](2+) cation (phen = 1,10-phen-anthroline), one [Fe(2)Cl(6)O](2-) anion and one half-mol-ecule of ethanol. In the cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. In the bent anion, two Fe(III) atoms are connected by a bridging oxide O atom [bridging angle = 160.6 (4)°], and each Fe(III) atom is also coordinated by three Cl atoms, completing a distorted tetra-hedral geometry.

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Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]

In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, formi...

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008